Murray and Robson, who have previously played together at the Hopman Cup in Australia, were given one of four wild card places available in the 16-pair draw.
Mixed Doubles is making its first appearance in the Olympics since 1924, when the gold medal was won by America's Hazel Wightman and Richard Williams, who was a survivor of the sinking of the Titanic.
Murray is the only one of the top four men to play, but the world's top two women players, Victoria Azarenka and Agnieszka Radwanska, will be in action for Belarus and Poland respectively.
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