Spain lost Santi Freixa to a broken arm in their opening draw with Pakistan and their next most-experienced player Pol Amat sustained a suspected dislocated shoulder today.
The team have taken one point from two matches, while Australia top Pool A with six points.
World number ones Australia stepped up a gear from their 6-0 win over South Africa and were ahead early on when Russell Ford produced an expert near-post finish from Mark Knowles' pass.
Matt Butturini added a second with a shot on the turn and Simon Orchard converted Matt Gohdes' cross to make it 3-0 at half-time, by which time Amat had departed.
A brilliant 50-yard aerial ball out from the back by Chris Ciriello sent Glenn Turner racing through to score the fourth and then Edward Ockenden deflected in Ciriello's slapped pass from a penalty corner, with defender Ciriello then hitting a post with another set-piece.
The match became increasingly niggly in the second half as Spain's frustrations grew but Australia's dominance was underlined by the statistics, which recorded 21 shots on goal.
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